(μ-2-Pyridinealdazine-κ4 N,N′:N′′,N′′′)bis[bis(N,N-di-n-propyldithiocarbamato-κ2 S,S′)cadmium(II)]
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منابع مشابه
Di-μ-hydroxido-κ4 O:O-di-μ-perchlorato-κ4 O:O′-bis[(2,2′-bipyridine-κ2 N,N′)copper(II)]
In the title binuclear copper(II) complex, [Cu2(ClO4)2(OH)2(C10H8N2)2], the Cu(II) ion is coordinated in the form of a Jahn-Teller distorted octahedron by two bi-pyridine N atoms, two perchlorate O atoms and two hydroxide O atoms, and displays a distorted octa-hedral geometry. The mol-ecule belongs to the symmetry point group C 2h . The Cu(II) ion is located on a twofold rotation axis and the h...
متن کاملDi-μ-acetato-κ4 O:O′-bis{[2-(2-pyridyl)phenyl-κ2 C,N]palladium(II)}
In the title complex, [Pd(2)(C(11)H(8)N)(2)(C(2)H(3)O(2))(2)], each Pd(II) ion has a distorted square-planar environment, being surrounded by one C, one N and two O atoms. The Pd⋯Pd distance is 2.8721 (3) Å. In the crystal structure, the mol-ecules are linked by inter-molecular C-H⋯O inter-actions.
متن کامل(μ-2-Pyridinealdazine-κ4 N,N′:N′′,N′′′)bis[bis(N,N-di-n-propyldithiocarbamato-κ2 S,S′)cadmium(II)]
The dinuclear centrosymmetric title compound, [Cd(2)(C(7)H(14)NS(2))(4)(C(12)H(10)N(4))], features a tetra-dentate 2-pyridine-aldazine ligand that chelates two Cd centres. The coordination geometry for Cd is distorted octa-hedral based on a cis-N(2)S(4) donor set. In the crystal structure, mol-ecules are connected into a supra-molecular chain aligned along the a direction via C-H⋯S and C-H⋯π co...
متن کاملcatena-Poly[[(1,10-phenanthroline-κ2 N,N′)praseodymium(III)]-di-μ-phenoxyacetato-κ4 O:O′-[(1,10-phenanthroline-κ2 N,N′)praseodymium(III)]-di-μ-phenoxyacetato-κ4 O:O′-di-μ-phenoxyacetato-κ3 O,O′:O;κ3 O:O,O′]
The title complex, [Pr(2)(C(8)H(7)O(3))(6)(C(12)H(8)N(2))(2)](n), which has an inversion centre midway between the two Pr(III) atoms of the structural unit, forms a one-dimensional polymer bridged alternately by either two bidentate, or two bidentate and two terdentate, phenoxy-acetate carboxyl-ate groups. Each Pr(III) atom is thus nine-coordinated by two N atoms of a 1,10-phenanthroline ligand...
متن کاملDi-μ-acetato-κ4 O:O′-bis[(1,10-phenanthroline-κ2 N,N′)(trifluoromethanesulfonato-κO)copper(II)]
The complete molecule of the title compound, [Cu2(C2H3O2)2(CF3O3S)2(C12H8N2)2], is completed by the application of a twofold rotation and comprises two Cu(II) ions, each of which is penta-coordinated by two N atoms from a bidentate 1,10-phenanthroline (phen) ligand, two O atoms from acetate ligands and an O atom from a tri-fluoro-methane-sulfonate anion, forming a (4 + 1) distorted square-pyram...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2008
ISSN: 1600-5368
DOI: 10.1107/s1600536808025889